Microenvironment Modulation in Metal–Organic Framework-Based Catalysis
نویسندگان
چکیده
منابع مشابه
Catalysis by framework zinc in silica-based molecular sieves
Microporous and mesoporous zincosilicates (e.g., CIT-6, VPI-8, Zn-MFI, and Zn-MCM-41) synthesized in the presence of alkali cations contain two broad types of Zn sites: one that is a dication analog of the monocation ion-exchangeable Al-site in aluminosilicates, while the other resembles isolated Zn sites on amorphous silica. The ratio of these sites varies, depending on the synthesis condition...
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ژورنال
عنوان ژورنال: Accounts of Materials Research
سال: 2021
ISSN: 2643-6728,2643-6728
DOI: 10.1021/accountsmr.1c00009